Interactable Pokémon

Like all Pokémon games, there's a myriad of Pokémon you'll find in the overworld. These Pokémon are exclusive to these methods so can only be found here, some on specific days or times

Drifloon

Location: Valley Windworks
Conditions: Friday Only

After you have defeated Team Galactic in the Valley Windworks, the Windworks manager will say that the Pokémon that appears may start appearing again. From the following Friday and every Friday afterwards, you will now find Drifloon floating outside the Valley Windworks.

Drifloon
Level 22
OT:Yours
ID:Yours
Ability:Aftermath or Unburden
??? Nature.
Date of Receiving
Valley Windworks. Level Met: 22
Focus Energy
Payback
Hex
Shadow Ball
Drifloon in Pokémon Brilliant Diamond & Shining Pearl

Spiritomb

Location: Route 209
Conditions: Grand Underground Interactions

If you find an Odd Keystone, either through the Grand Underground or otherwise, you can place it in the mysterious cumbled Hallowed Tower in Route 209. From there, if you interact with NPCs in the Grand Underground, it will build the energy to unleash Spiritomb. You need to have interacted with 32 different people in order to get Spiritomb. When you interact with the Hallowed Tower before then, you will get a message which can indicate how close you are

0-7 people - "It appears to have been built many years ago."
8-14 people - "Its stones appear to have shifted..."
15-21 people - "...Is that crying coming from inside the tower?"
22-28 people - "Is the tower shaking ever so slightly?"
29-31 people - "There is some sort of presence... It appears ready to emerge!"

Click here for details on Underground NPCs

Spiritomb
Level 25
OT:Yours
ID:Yours
Ability:Pressure
??? Nature.
Date of Receiving
Route 209. Level Met: 25
Spite
Payback
Nasty Plot
Hex
Spiritombin Pokémon Brilliant Diamond & Shining Pearl

Rotom

Location: Old Chateau
Conditions: Night

After you have the National Pokédex, if you go to the Old Chateau, if you go to it at night and interact with the TV in one of the rooms on the second floor, you will be able to get the Pokémon Rotom. Once defeated, you'll receive the Secret Key which you can take to the Eterna Galactic Building to change Rotom's form, getting the Rotom Catalogue when you enter the first form, and being able to change form to whichever you have had Rotom enter

Rotom
Level 15
OT:Yours
ID:Yours
Ability:Levitate
??? Nature.
Date of Receiving
Old Chateau. Level Met: 15
Double Team
Thunder Shock
Confuse Ray
Charge
Rotom in Pokémon Brilliant Diamond & Shining Pearl